All, Thank you for your input and all of the suggestion. Upon further and very detailed investigation, It was discovered that McAfee was the root cause of my issues.
If you encounter similar errors when sending emails, check the following on your computer:
Go to your quick tool bar and select the "McAfee" icon, then select "Manage Features"
Double click on "Access Protection"
Click on "ANti-virus Standard Protection"
Look for the line item "Prevent Mass Mailing worms from sending mail"
If you have a check mark under the "Block" column, then you will need to un-check it. If your on a corporate network, your "IT" manager will need to log into your McAfee and un-check this option. Once that is completed, you should be able to send emails through Access without issue.