I also tried using datediff:
SELECT Max(ID) FROM Shifts WHERE ShiftType = 3 AND Weekdaynumber = 2 AND Werk = 2101 AND Datediff('n',Start, #13:08:14#) < 0;
And
SELECT Max(ID) FROM Shifts WHERE ShiftType = 3 AND Weekdaynumber = 2 AND Werk = 2101 AND Datediff('n',TimeValue([Start]), #13:08:14#) <...