Now is the time to be very careful.
What is it that you wish to do? Do you wish to display 0 when the field is Null, or do you wish to replace all Nulls with 0.
The latter is best done with a query, but it will then alter the values permanently
update mytable set myfield = 0 where myfield is null
the first can easily be achieved by altering the format of either the field or control in question.
Playing with the format, numbers can have four formats, where the first is format when positive, the second is format if negative, the third is format when 0, the fourth is format when Null. So, let's say you're doing thousand separator, then you could try pasting this into the format property of either the field or control
#,##0.00;[Red]-#,##0.00;0;0