3 things all pertaining to Appointment TS, the last of which deals with the issue you have:
1. 'Time' is a reserved word and therefore a poor choice for a field name. Long story short, it makes coding and writing queries more difficult. (You should also remove spaces in table/field names for this reason too.) Usually you want to prefix data like this (Date, Time, Name) with what it represents (e.g. ApptDate, ApptTime, PatientName, etc.). However...
2. Look at Appointment TS in design view. You will see that the Appointment Date has a Data Type of Date/Time. That means it can hold both date and time in that one field. Instead of an Appointment Date and a Time field you should store this information in one field (AppointmentTime).
3. You already have Customer ID field in Appointment TS, so you don't need any other data from Customer TS in that table. With that Customer ID you can create a query and link those two tables together and get all the data in them together. That is how you get the Full Name and Appointment data together, not by assigning it a value to a field inside Appointment TS.