You can set the OrderBy property in the form's properties. Access help has some examples.
This is taken directly from the help files:
The OrderBy property is a string expression that is the name of the field or fields on which you want to sort records. When you use more than one field name, separate the names with a comma (,).
When you set the OrderBy property by entering one or more field names, the records are sorted in ascending order. Similarly, Visual Basic sorts these fields in ascending order by default.
If you want to sort records in descending order, type DESC at the end of the string expression. For example, to sort customer records in descending order by contact name, set the OrderBy property to "ContactName DESC".
HTH