I'm going to step away from the previous post to talk "overview" because right now you are still gathering facts. There will be tons of things to consider and your best bet is to try to stay methodical in what you do. Divide and conquer. Do your fact-finding in a way that allows you to separate what you learned according to relevant topics.
There are a few guidelines I can offer and they won't entirely make sense right away perhaps. But I'll explain and hope that they will be "food for thought" when you are designing.
Rule #1 - If you can't do it on paper, you can't do it in Access. That is, if you don't understand the processes well enough to draw a diagram of where data originates, where/how it is processed, and where it goes, then you aren't ready to actually build anything other than as a "trial balloon." If you can put a diagram on paper, you have a roadmap. This is important because if you don't have a map to where you are going, how do you think you will ever find it, or know that you HAVE found it? Without this roadmap, you have no target and if you shoot from the hip, you will find out how lousy a shot you can be. It can be an eye-opening experience.
Rule #2 - Access can't tell you anything you didn't provide to it first. That is, Access knows NOTHING except how to make tables, queries, forms, reports, macros, and modules - and relationships. But it knows nothing about YOUR business at all. So YOU will be providing the inputs that become your working data sets. If you want to see XYZ coming out of your database, you have to provide it with XYZ somewhere, or at least you have to give it X, Y, and Z and the formula that combines them. This rule sometimes means that you have to work backwards from the desired outputs to verify that you have the inputs you need to make this DB work.
Rule #3 - When your Access Database says X and yet the real-world process says Y, the database is wrong. That is, reality always wins. When you plan your DB to do things, be sure that you are planning something that corresponds to the real-world process. Otherwise you will reach the point where either (a) your database forces a business process change (the tail is wagging the dog) or (b) your database becomes useless because it diverges too much from reality. Neither of those is good.