I've spent 50+ years designing and developing business applications using relational databases and probably used 1-1 relationships 3 times. They are EXTREMELY rare and NEVER created because your table is too wide. As the others have suggested, if your table is too wide, it is almost certainly in need of normalization. Look for sets of fields with prefixes or suffixes, especially numeric ones. Sometimes the repeating groups are harder to spot because the names are all different. How about, electric, gas, oil, water, snow shovelling, lawn mowing, cable, etc. Can you identify the pattern even though the names are all different?
But just to be complete, in a 1-1 relationship, one of the tables is the "master". It is the one with the autonumber PK and it is always inserted first. The "child" table uses a long integer as it's PK and that same field is also the FK to the "master".
On indexes:
There are two ways to create indexes. One method is used for single field indexes and the second is used for multi-field indexes.
Open the table in design view
1. Use the Index property for single field indexes.
2. Open the indexes dialog to create multi-field indexes. Give the first row a name and set the property to unique if necessary. Then for each subsequent row, leave the name blank. Access supports a MAXIMUM of 10 fields in an index. SQL Server allows
View attachment 103809 32 I think.