Spend a couple hours figuring out relational database design
Here's a pretty good link off of the Microsoft Support Knowledge Base; there are others:
http://support.microsoft.com/default.aspx?scid=kb;en-us;Q100139
Basically the thing to remember is that Access understands 0, 1, or Many of something. If something
can have many, it should be stored in another table so it has room to grow, so to speak.
If a calculation cannot be replicated later, it should be stored. If it can be reproduced later from existing data, don't store it but instead calculate it on a form or query.
It sounds like, if I understand correctly, you're concerned with tracking comissions for salespeople, on orders. You mention storing more data about the order but that's a larger issue; are you going to be duplicating data to do so (i.e. are you storing it elsewhere in your system?), or are you thinking of migrating over to Access entirely?
So an order can have more than one invoice possibly, and one or more commissions are tracked from the closed invoices, right?
If so, you'll need four tables so far (make sure each has its own Primary Key).
One to deal with Orders (also called Jobs?). This should store information that is the same for the entire order.
One to deal with Invoices. Include all the invoice-specific material, but make sure you include a field of the same basic type as your PK field from Orders. This allows you to create a one-to-many relationship that associates certain invoices with a specific order.
One to keep track of your Salespersons. This one includes their personnel data you might need for this function (like do they get different rates based on seniority, job function, etc?). Don't worry about linking this to the other tables yet.
That's the job of the fourth table. Because any One Invoice can have Many Salespersons associated with it, and One Salesperson can (we hope) have Many Invoices they've been involved with, you've got a Many-to-Many relationship. For this you need a linking table. All it does is store the association between a specific Salesperson and a specific Invoice, so your queries can figure it out later. Two fields are needed: PK from Salespersons, and PK from Invoices. You can Shift-click on both of them in design view of the table and make them a multi-part Primary Key for this table; this means you can never duplicate that combination of Salesperson with that Invoice again. If this isn't appropriate to your work then just put an Autonumber PK in like usual.
Hopefully that will give you a start. Make sure you read up on defining relationships, referential integrity, and using related tables in queries. Post back if you need more help, or check the archives.