If your using 2007, which you stated in your first post, you do not need any additional converter. 2007 has the ability to send in pdf format. I'm not sure how you would do this with a form.... Forms are to input and view data, not meant to be used as a document... Thats what reports are for. If you like how it looks simply design a report to look like your form.
And then Yes, you could make it print and send as an email attachment by clicking one button. You would simply combine onclick event code of the buttons into one button..... something like...
Private Sub cmdPrint_Click()
Dim stDocName As String
stDocName = "rptCurrent"
DoCmd.OpenReport stDocName, acNormal
DoCmd.SendObject acSendReport, stDocName, "acFormatPDF", "email@whatever.com", "", "", , " ", False, ""
something like that. Or if you wanted to keep a separate button for printing you could just use
Call cmdPrint
Docmd.Sendobject..............