The primary and foreign keys are created at the tables and yes, you can create these after the fact. If you look at the relationships screen (you might have to right-click and do a 'show all'), it should reveal if there are any relationships set up. If not, you can create these yourself.
Whoever did all of this for you might be manually doing the linking so you might have to analyze all of the code in and around the forms to check it out.
You can do things like use the query wizard to look for duplicate or unmatched fields from table to table to help you rationalize what is going on. It sounds like the description wasn't use on the table to define each field for you.
Most of all though, make a copy of the database and use that to experiment on - don't wreck your production copy until you are for sure know what you are doing, what you want to do and the steps to accomplish the objectives.
-dK