It's realy hard to understand what you you want here.
they are both in the table, so why should you write them into the table ? or do you mean writing both of them into another table ?
writing both values into another table is not normaly advised, cause you creat a redundent data - you double your data.
though there are case you do want to do it, like copying the price together with the product into a table that store buyer data, cause you want to keep the price he paid in case price of product will be changed.
even for this there are some more "correct" ways to do it, though they are more omplex like keeping all the price history of the product.
now after all this philosopy

if this is what you want - copy both columns into another table you can do it as rodich said -
first column = Me.myList.Column(0)
second column = Me.myList.Column(1)
use the change events of the List Box to copy the data to the correct fields, like:
me.FieldName = me.ListBox.Column(0)
but if you only want to display both column....

also as rodich said -
in the number of columns property set it to 2, and set the width of the columns, like 2;5
don't forget to bound your data to the correct column.