OK the best solution I can come up with is, in the new field in design view on the query, wirte a series of nested If(IIf) statements. Basically you need to test ALL the options to find out which is the greatest.
I don't know how you are with IF statements, but if you've never done them before start small (just test a few variables) so you can work out how they think.
IIf(Valiable1 is GreaterThan Variable2 then DoThis, Else DoThis)
Thats the structure
IIf(Mon > Tues, "Monday is the greatest", "Tuesday is the greatest")
Thats a basic statement
Instead of writing the text as a result, what you need to do put in more tests, ie instead of "Monday is..." you need to put IIF(Mon > Wed ... etc It'll be very long and complicated though.
IIf(Mon > Tues, (IIF(Mon > Wed ,"Monday is the greatest",), "Tuesday is the greatest")
And having writen all that I checked in the help files and found the
DMax(expr, domain[, criteria]) function.
I've never used so I don't know if it'll do what you want.
Good luck