If every field begins with "CON WD ", there's no reason to sort by those characters: Sort using just the characters after "CON WD ".
Try:
SortCode:Format(Mid(tMyTableFieldName, 8), "0000000000")
using a query with your table as the record source and sort the SortCode field ascending.
The limiting factor for sorting "correctly" is the arbitrarily large string of consecutive "0" characters in the Format function call.
If you need to sort with the leading characters, just concatenate the Format function results to the parsed leading charactrers:
SortCode:Mid(tMyTableFieldName, 1, 7) & Format(Mid(tMyTableFieldName, 8), "0000000000")