That's not the typical request. Usually, someone has a table of employees or customers. And they want to identify the location (say Country) of each Customer.
In that case, there are usually 2 tables. A Customer table and a CountryLookup table.
The CountryLookup table has fields such as
CountryID and CountryName with values such as
1 United States
2 Great Britain
3 Australia
4 Canada
.....
When completing a form with Customer records, a list box or combo box of CountryNames would be available. One would select a Country from the list, and the CountryID would be placed in the Customer table.
City and State example:
A variation is to have 2 combo boxes in the case of Cities and States.
Combo1 has a list of States, Combo2 has a list of City*States
One would select a State from Combo1, and behind the scene only Cities in the Selected State would be available for selection in Combo2. In effect a filter has been placed on Combo2, based on the value selected from Combo1. (This is known as Cascading Combos)
Once the City is selected, the State Code and The city code/name would be added to the table.
Is that what you are looking for?